| วัตถุประสงค์
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1. To synthesize cyanometallate [MTpR(CN)3]- (R = Me3, Ph2; M = Fe, Co) and [MTpR(CN)2]- (R = Me3, Ph2; M = Co, Ni) complexes as precursors for magnetic materials.
2. To prepare molecular magnets of the general formula [MTpR(CN)3M Ln]m (M = Fe; R = Me3, Ph2; M = Mn, Fe, Co, Ni, Cu; m =1, 2, 3, 4; L = solvent, chelating ligand, tripodal ligand) and investigate their electrochemical and magnetic properties.
3. To synthesize molecular magnets of the general formula [MTpR(CN)3M Ln]m (M = Fe; R = Me3, Ph2; M = Tb, Gd, Nd, Eu and Dy; m =1, 2, 3, 4; L = solvent, chelating ligand) and investigate their electrochemical, optical and magnetic properties.
4. To synthesize and characterize [MTmRX] (M = Fe, Co, Ni; R = Me, Ph, t-Bu, X = N3-, SCN-, NO2-, NO3-, OAc-, acac-) or [MTmR(L)]+ (M = Fe, Co, Ni; R = Me, Ph, t-Bu; L = pyridine, pyrazine, bipy, phen, en, dppm, dppe).
5. To prepare and characterize novel cyanometallates [MTmR(CN)3]- (M = Fe, Co; R = Me, Ph, t-Bu) and [MTmR(CN)2]- (M = Co, Ni; R = Me, Ph, t-Bu).
6. To explore the chemistry of magnetic clusters of the general formula [MTmR(CN)3M Ln]m (M = Fe; R = Me, Ph, t-Bu; M = Mn, Fe, Co, Ni, Cu; L = solvent, chelating ligand, tripodal ligand) and investigate their electrochemical and magnetic properties.
7. To train a new generation of Thai researchers in nanotechnology.
8. To publish 2 or 3 international research papers based upon this research.
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